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杜延军, 蒋宁俊, 王乐, 魏明俐. 水泥固化锌污染高岭土强度及微观特性研究[J]. 岩土工程学报, 2012, 34(11): 2114-2120.
引用本文: 杜延军, 蒋宁俊, 王乐, 魏明俐. 水泥固化锌污染高岭土强度及微观特性研究[J]. 岩土工程学报, 2012, 34(11): 2114-2120.
DU Yan-jun, JIANG Ning-jun, WANG Le, WEI Ming-li. Strength and microstructure characteristics of cement-based solidified/stabilized zinc-contaminated kaolin[J]. Chinese Journal of Geotechnical Engineering, 2012, 34(11): 2114-2120.
Citation: DU Yan-jun, JIANG Ning-jun, WANG Le, WEI Ming-li. Strength and microstructure characteristics of cement-based solidified/stabilized zinc-contaminated kaolin[J]. Chinese Journal of Geotechnical Engineering, 2012, 34(11): 2114-2120.

水泥固化锌污染高岭土强度及微观特性研究

Strength and microstructure characteristics of cement-based solidified/stabilized zinc-contaminated kaolin

  • 摘要: 采用水泥作为固化剂对锌污染高岭土进行固化稳定处理,对固化后养护7 d和28 d的人工锌污染土的液塑限特性,无侧限抗压强度和变形模量特性,土样pH特性,以及微观机理进行了研究.结果表明,液塑限随锌离子浓度增加而降低.随锌离子浓度增加,固化污染土的无侧限抗压强度值总体均呈下降趋势;随试样pH值升高,无侧限抗压强度值增大;变形模量E50均随锌离子浓度增大而减小;水泥的主要水化产物的数量均随锌离子浓度的增加而减少,且由成熟形态向早期形态退化,并最终消失.随着锌离子浓度的增加,试样中的直径1~10 μm的孔隙数量明显增加,并且伴随着直径0.01~1 μm的孔隙数量的减小.

     

    Abstract: An experimental investigation of Atterberg limits, unconfined compressive strength, secant modulus, pH of soil and microstructure characteristics of cement-treated zinc-contaminated kaolin is presented. The zinc-contaminated soils are artificially prepared with various zinc concentrations (0%, 0.01%, 0.02%, 0.05%, 0.1%, 0.2% and 0.5%), cement contents (8%, 12%, 15%, and 18%), and curing time (7 d and 28 d). The test results of Atterberg limits show that the liquid limit and plastic limit decrease with the increase of the initial zinc concentration in the soils. The unconfined compressive strength decreases with the increase of the initial zinc concentration. The pH values of the soils are significantly affected by the initial zinc concentration. The secant modulus (E50) decreases as the initial zinc concentration increases. The scanning electron microscope pictures show that as the initial zinc concentration increases, the quantity and morphology of major cement hydration products change significantly. The test results of mercury intrusion porosimetry demonstrate that with the increase of the initial zinc concentration, the quantity of soil pores with diameter of 1 to 10 μm increases, whereas that of pores with diameter of 0.01 to 1 μm decreases.

     

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