酸性环境中钙质胶结砂岩的化学损伤模型
A chemical damage model of sandstone in acid environment
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摘要: 针对大部分工程中常见的砂岩最可能、最不利的化学环境———酸性环境中的力学性质的衰变、弱化问题,对钙质胶结长石砂岩进行了室内不同pH值溶液的模拟试验,对所得到的抗压强度试验及CT扫描试验结果进行了分析与总结,发现砂岩中主要胶结物CaCO3的溶解是岩石强度和变形衰减的主要原因,在此基础上利用化学动力学理论和损伤力学理论提出了可应用于酸性溶液的岩石化学损伤强度模型,并用室内实验结果对所提模型进行了检验与验证。Abstract: Aimed at the degradation of the mechanical properties of the sandstone in the acid environment, the experiments of the feldspathic sandstone samples submerged in various acid solutions with different pH values are carried out. The mechanism of chemical reaction is also revealed with analyzing the results of compression test and CT scanning. The solution of the main cement of rock-CaCO3 is considered as the reason of the degradation of the strength and deformation properties of the rock. A strength model for chemical damage of rock in the acid solution is then established using theories of chemical kinetics and damage mechanics,and examined using the experiment results.