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李敏, 于禾苗, 赵末炎, 张学超, 路通, 吴海铭. 协同固化作用下石油污染土的粘温效应研究[J]. 岩土工程学报. DOI: 10.11779/CJGE20240354
引用本文: 李敏, 于禾苗, 赵末炎, 张学超, 路通, 吴海铭. 协同固化作用下石油污染土的粘温效应研究[J]. 岩土工程学报. DOI: 10.11779/CJGE20240354
Study on viscosity-temperature effect of petroleum-contaminated soil under synergistic solidification[J]. Chinese Journal of Geotechnical Engineering. DOI: 10.11779/CJGE20240354
Citation: Study on viscosity-temperature effect of petroleum-contaminated soil under synergistic solidification[J]. Chinese Journal of Geotechnical Engineering. DOI: 10.11779/CJGE20240354

协同固化作用下石油污染土的粘温效应研究

Study on viscosity-temperature effect of petroleum-contaminated soil under synergistic solidification

  • 摘要: 温度影响着土中石油污染物的赋存形态,是引发结构失稳和环境二次污染的关键因素,石油污染土粘温特性的合理调控是推进其工程再利用过程中需解决的科学问题。提出粘度指数改进剂协同无机材料进行石油污染土固化的处置方法,依托流变仪及改进的温控直剪蠕变和液塑限联合测定试验平台,从石油及石油污染土双重角度,分析粘度指数、粘滞系数和稠度指标随温度的演变规律,评价粘温效应,构建粘温特性调控方法。结果表明:石油及石油污染土的粘性状态均受温度影响显著,同污染浓度下石油污染土在20 ℃温差下的塑性指数变化率高达31.83%,且其在80 ℃下的粘滞系数较10 ℃ 的平均降低率为53.82%。粘度指数改进剂有助于增大石油粘度指数,改善石油温敏性。7% T614(乙丙共聚物)+7% T602HB(聚甲基丙烯酸酯)协同无机材料固化石油污染土相邻温度间粘滞系数和稠度指标变化率范围均在5%以内,且10~80 ℃温度下总体变化范围在10%以内。协同固化作用下的调控率(达85.42%)均高于单一固化方式的累加,粘度指数改进剂和无机材料在调控效能方面相辅相成,改进剂优化土中石油分布,解决石油对固化反应的干扰,提升吸附和固化反应充分性;无机材料固化优化土体结构,增强了改进剂与石油间的作用效果。粘度指数改进剂与无机材料的协同固化实现了石油污染土宽温域范围的调控,有助于提升其工程再利用过程中的稳定性。

     

    Abstract: Temperature affects the occurrence form of petroleum contaminants in the soil, which is a key factor causing structural instability and secondary environmental contamination. The reasonable control of the viscosity change under temperature is a scientific problem for the engineering reuse of petroleum-contaminated soil. The method of viscosity index improvers combined with inorganic materials for solidifying petroleum-contaminated soil was proposed in this study. The evolution of the viscosity index, viscosity coefficient, and consistency index with temperature was analyzed from the perspective of petroleum and petroleum-contaminated soil. The viscosity-temperature effect was evaluated and its regulation method was constructed. The results showed that the viscosity of petroleum and petroleum-contaminated soil is significantly affected by temperature. The plastic index change rate of petroleum-contaminated soil at 20 ℃ was as high as 31.83%, and the viscosity coefficient at 80 ℃ was 53.82% lower than that at 10 ℃. The viscosity index improver is helpful in increasing the viscosity index of petroleum and improving its occurrence stability. As for petroleum-contaminated soil solidified by 7% of T614 (ethylene propylene copolymer), 7% of T602HB (polymethyl methacrylate), and inorganic material, the change rate of viscosity coefficient and consistency index of between adjacent temperatures was within 5% and the overall change range from 10 ℃ to 80 ℃ was within 10%. The regulation rate under the synergistic solidification (85.42%) was higher than the accumulation of the single solidified method. The viscosity index improvers and inorganic materials complemented each other in the regulation efficiency. The improver optimizes the petroleum distribution in the soil, which could improve the sufficiency of adsorption and solidified reaction. Meanwhile, the solidification of inorganic materials enhanced the density of soil structure and strengthened the action of the viscosity index improvers and petroleum. The synergistic solidification of viscosity index improvers and inorganic materials realizes the regulation of petroleum-contaminated soil in a wide temperature range, which helps to improve the stability of petroleum-contaminated soil in the process of engineering reuse.

     

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