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汪恩良, 李宇昂, 任志凤, 姜海强, 刘承前, 邹亦云, 杜世林. 基于扫描电镜和核磁共振技术的分散性土改良微观结构性变化研究[J]. 岩土工程学报, 2023, 45(6): 1123-1132. DOI: 10.11779/CJGE20220331
引用本文: 汪恩良, 李宇昂, 任志凤, 姜海强, 刘承前, 邹亦云, 杜世林. 基于扫描电镜和核磁共振技术的分散性土改良微观结构性变化研究[J]. 岩土工程学报, 2023, 45(6): 1123-1132. DOI: 10.11779/CJGE20220331
WANG Enliang, LI Yuang, REN Zhifeng, JIANG Haiqiang, LIU Chengqian, ZOU Yiyun, DU Shilin. Microstructural change of improved dispersive soil based on scanning electron microscope and nuclear magnetic resonance technology[J]. Chinese Journal of Geotechnical Engineering, 2023, 45(6): 1123-1132. DOI: 10.11779/CJGE20220331
Citation: WANG Enliang, LI Yuang, REN Zhifeng, JIANG Haiqiang, LIU Chengqian, ZOU Yiyun, DU Shilin. Microstructural change of improved dispersive soil based on scanning electron microscope and nuclear magnetic resonance technology[J]. Chinese Journal of Geotechnical Engineering, 2023, 45(6): 1123-1132. DOI: 10.11779/CJGE20220331

基于扫描电镜和核磁共振技术的分散性土改良微观结构性变化研究

Microstructural change of improved dispersive soil based on scanning electron microscope and nuclear magnetic resonance technology

  • 摘要: 分散性土是一种在低含盐量水中易分散解体的特殊性黏土,这一特性导致了许多水利与岩土工程的失稳与破坏,分散性黏土在中国东北地区分布广泛。为了改良分散性黏土抗冲蚀能力,探索分散性土孔隙结构演化特征,分析木质素改良分散性土作用机理,以黑龙江省南部引嫩工程分散土为研究对象,通过分散性鉴别试验、扫描电镜(SEM)试验与核磁共振(NMR)试验对不同木质素掺量(0%~10%)的分散性、元素组成与微观结构进行测试与观察。试验结果表明:①木质素可有效改良分散土分散性,木质素掺量≥3%且养护龄期≥7 d即可有效加强土体抗冲蚀能力。②SEM图像分析与NMR试验具有较好的一致性,随着木质素掺量增加,土体中微小孔隙逐渐发育成大孔径孔隙,孔隙率呈先减小后增大的趋势,在冻融循环作用下,土体中大孔径孔隙呈增加趋势,对木质素掺量≤5%的改性土影响更为显著。③木质素中的Ca2+与土体中Na+发生离子交换反应,可吸附在土体表面并形成一层疏水层,提高土体的抗冲蚀能力,但木质素掺量过多,其自带的磺酸基相互吸附,导致土体黏度增加,难以压实,形成大孔缺陷。结果表明,适量的木质素可对分散土产生良好的改性效果,填充土体孔隙,提高土体的抗冲蚀能力,可为分散土孔隙结构与实际工程性能提供理论参考。

     

    Abstract: The dispersive clay is a special clay that is easy to disperse and disintegrate in low salt water. This characteristic leads to the instability and failure of many water conservancy and geotechnical projects. The dispersive clay is widely distributed in Northeast China. In order to improve the erosion resistance of the dispersive clay, explore the evolution characteristics of pore structure of the dispersive soil and analyze the action mechanism of the lignin-improved dispersive soil, the dispersive soil of Nenjiang River Diversion Project in the south of Heilongjiang Province is taken as the research object, and the dispersity, element composition and microstructure of different lignin contents (0%~10%) are tested and observed through the dispersity identification tests, scanning electron microscope (SEM) tests and nuclear magnetic resonance (NMR) tests. The test results show that: (1) The lignin can effectively improve the dispersibility of the dispersive soil. The anti-erosion capability of the soil can be effectively strengthened if the lignin content is≥3% and the curing age is≥7 days. (2) The SEM image analysis and the NMR tests have good consistency. With the increase of the lignin content, the micro-pores in the soil gradually develop into large pores, and the porosity first decreases and then increases. Under the action of freeze-thaw cycle, the large pores in the soil show an increasing trend, which has a more significant impact on the modified soil when the lignin content ≤ 5%. (3) Ca2+ in lignin reacts with Na+ in the soil by ion exchange, which can be adsorbed on the surface of the soil and form a hydrophobic layer to improve their erosion resistance. However, due to the excessive lignin content and mutual adsorption of its own sulfonic acid groups, the viscosity of the soil increases, and it is difficult to compact and form macroporous defects. The appropriate amount of lignin can produce a good modification effect on the dispersive soil, fill the soil pores and improve the erosion resistance of the soil, which may provide a theoretical reference for the pore structure and practical engineering performance of the dispersive soil.

     

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