活性MgO碳化生土砌块材料配比与机理研究
Ratio and mechanism of activated magnesium oxide carbonized raw earth block materials
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摘要: 通过单因素条件下抗压强度试验、X射线衍射试验和扫描电镜试验,研究了不同材料掺量和含水率影响下,活性MgO碳化生土砌块的强度和微观形态的变化规律。结果表明:活性MgO碳化生土砌块的原材料配合比MgO∶水泥∶粉煤灰∶生土为7∶7∶6∶80时,按照生土基材最优含水率加入清水混合后,制作而成的砌块抗压强度较高,其21天抗压强度值趋于平稳,平均值能达到7~8 MPa左右;微观测试表明,活性MgO水泥水化和碳化反应,生成的镁式碳酸盐其自身的强度、胶结性能和对孔隙的填充是砌块强度增长的主要原因。Abstract: By means of the single-factor compressive strength tests, X-ray diffraction (XRD) tests and scanning electron microscope (SEM) tests, the variation rules of strength and microscopic morphology of the activated magnesium oxide (MgO) carbonized raw earth blocks under the influences of different material contents and water contents are studied. The results show that when the mixture ratio of raw materials of the active MgO-carbonized raw soil blocks is 7:7:6:80 MgO: cement: fly ash: raw soil and water is added according to the optimal moisture content of raw soil substrate, the compressive strength of the blocks prepared is higher, and the 21-day compressive strength tends to be stable, with an average value of about 7~8 MPa. The XRD and SEM tests show that the strength, cementing property and pore filling of magnesium-type carbonate generated by hydration and carbonation reaction of the active MgO cement are the main reasons for the increase of strength of the blocks.