相变材料改良膨胀土冻融性能试验研究及微观机理分析
Experimental study and micro-mechanism analysis of freeze-thaw performance of expansive soils improved by phase-change materials
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摘要: 季冻区膨胀土经历的复杂冻融过程会造成土体冻融性能的劣化。相变材料在相变过程中能够以潜热的形式储存和释放大量能量,可用于改良土体的冻融性能。以北疆高寒地区渠基膨胀土为研究对象,室内模拟渠道沿线实际气候条件的冻融循环试验,选用石蜡基液体相变材料(pPCM)和石蜡基微胶囊相变材料(mPCM),对经历冻融循环后不同相变材料掺入量的改良膨胀土进行体积变形试验、无侧限抗压强度试验、DSC热循环试验和SEM电镜扫描试验,结果表明:pPCM在一定程度提高了土体破坏时的韧性;在改善渠基土内部温度场,提升土体的热稳定性方面性能要略优于mPCM。mPCM可以降低土体的胀缩变形;有效抑制了土体强度的衰减,以8%的掺量最为显著;mPCM减小了冻融对土体微观孔隙损伤的影响,宏观上减弱了冻融循环对土体强度的衰减作用。试验研究表明,mPCM改良膨胀土在抵抗反复冻融循环问题上具有明显的优势,可为实际工程设计提供参考。Abstract: The complex freeze-thaw process experienced by expansive soils in seasonally frozen regions will cause the deterioration of freeze-thaw performance of soils. The phase-change materials can store and release a large amount of energy in the form of latent heat during the phase change process, and can be used to improve the freeze thaw performance of soils. For the case study of expansive soils in the canal base in high and cold regions of northern Xinjiang, the freeze-thaw cycle tests under the actual climatic conditions along the canal are conducted. The paraffin-based liquid phase-change material (pPCM) and the paraffin-based microcapsule phase-change material (mPCM) are selected. After undergoing freeze-thaw cycles, the modified expansive soils with different blending amounts of phase-change materials are subjected to the volume deformation tests, unconfined compressive strength tests, DSC thermal cycle tests and SEM tests. The results show that the pPCM can improve the toughness of soils under failure to some extent, and it is slightly better than mPCM in improving the internal temperature field of the foundation soils in the canal and improving the thermal stability of the soils. The mPCM can reduce the expansion and contraction deformation of the soils. It effectively inhibits the attenuation of the strength of the soils, and the mixing amount of 8% is the most significant. The mPCM reduces the impact of freeze and thaw on microscopic pore damage of the soils, and macroscopically weakens the attenuation effect of freeze and thaw cycles on soil strength. The tests show that the mPCM-modified expansive soils have obvious advantages in resisting repeated freeze-thaw cycles, which can provide a reference for the design of actual projects.