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王艳, 王爱骅, 刘干斌. 温控电动联合淋洗法去除污染淤泥质黏土中铬的试验研究[J]. 岩土工程学报, 2021, 43(8): 1542-1549. DOI: 10.11779/CJGE202108020
引用本文: 王艳, 王爱骅, 刘干斌. 温控电动联合淋洗法去除污染淤泥质黏土中铬的试验研究[J]. 岩土工程学报, 2021, 43(8): 1542-1549. DOI: 10.11779/CJGE202108020
WANG Yan, WANG Ai-hua, LIU Gan-bin. Experimental study on remediation of chromium-contaminated mucky clay by electrokinetic soil flushing method considering temperature[J]. Chinese Journal of Geotechnical Engineering, 2021, 43(8): 1542-1549. DOI: 10.11779/CJGE202108020
Citation: WANG Yan, WANG Ai-hua, LIU Gan-bin. Experimental study on remediation of chromium-contaminated mucky clay by electrokinetic soil flushing method considering temperature[J]. Chinese Journal of Geotechnical Engineering, 2021, 43(8): 1542-1549. DOI: 10.11779/CJGE202108020

温控电动联合淋洗法去除污染淤泥质黏土中铬的试验研究

Experimental study on remediation of chromium-contaminated mucky clay by electrokinetic soil flushing method considering temperature

  • 摘要: 自行设计了温控电动联合淋洗试验装置,开展了铬污染淤泥质黏土室内土柱试验,分析了电流、电解质溶液pH的变化以及淋洗液种类、外加电压、温度对铬去除效果的影响。结果表明:电动联合淋洗法可以有效去除土体中的重金属铬,当电压较小为15 V,淋洗液为十二烷基苯磺酸钠(SDS)和草酸(OA)时,Cr(Ⅵ)的去除率分别高达95.86%和95.91%,Cr(总)的去除率分别为81.31%和78.08%。升高温度有助于草酸与铬的络合作用及铬的迁移,当温度升高至45℃时,Cr(Ⅵ)与Cr(总)的去除率可高达99.65%与82.50%;而当淋洗液为SDS时,升高温度使Cr(总)的去除率降低了10.99%。电压提高到55V对铬迁移的促进作用有限,淋洗剂为SDS和草酸时,Cr(VI)的去除率分别提高2.58%和3.05%,Cr(总)的去除率分别提高9.29%和3.78%,从节能角度考虑可采用较低的电压。电动联合淋洗法可有效去除污染土中水溶态及弱酸提取态的铬,降低污染土的毒性,并使土粒之间的孔隙变小,土粒结构更为紧密。

     

    Abstract: A series of column tests on chromium-contaminated mucky clay are conducted in lab using the self-designed electrokinetic soil flushing apparatus considering temperature. The changes of the current and electrolyte solution pH, and the effects of the type of leaching agent, applied voltage and temperature on the removal behavior of chromium are analyzed. The results show that the chromium in soil can be removed effectively by the electrokinetic soil flushing method. When the voltage is 15 V, using sodium dodecylbenzene sulfonate (SDS) and oxalic acid (OA) as leaching agent, the removal ratio of Cr(VI) is 95.86% and 95.91% respectively, and the removal ratio of Cr (total) is 81.31% and 78.08% respectively. Raising temperature to 45℃ can promote complexation of oxalic acid and chromium leading to the migration of chromium, the removal ratio of Cr (VI) and Cr (total) reaches 99.65% and 82.50% respectively. However, raising temperature results in the removal ratio of Cr(total) by 10.99% when using SDS as leaching agent. Raising the voltage to 55 V, the chromium migration has slight effect on its migration. When using SDS and OA as leaching agents, the removal ratio of Cr(VI) can increase by 2.58% and 3.05% respectively, and that of Cr (total) can increase by 9.29% and 3.78% respectively. Lower voltage can be selected for the sake of saving energy. The water-soluble and weak acid-extracted chromium can be efficiently removed by the electrokinetic soil flushing method and the toxicity of contaminated soil can be reduced. After remediation, the soil structure is changed, and the pores between soil particles become smaller and the soil is more compacted.

     

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