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邹维列, 叶云雪, 韩仲. 基于化学反应动力学方程的一维膨胀时程模型[J]. 岩土工程学报, 2020, 42(4): 737-744. DOI: 10.11779/CJGE202004017
引用本文: 邹维列, 叶云雪, 韩仲. 基于化学反应动力学方程的一维膨胀时程模型[J]. 岩土工程学报, 2020, 42(4): 737-744. DOI: 10.11779/CJGE202004017
ZOU Wei-lie, YE Yun-xue, HAN Zhong. Chemical reaction kinetics based models for describing evolution of one-dimensional expansion with time[J]. Chinese Journal of Geotechnical Engineering, 2020, 42(4): 737-744. DOI: 10.11779/CJGE202004017
Citation: ZOU Wei-lie, YE Yun-xue, HAN Zhong. Chemical reaction kinetics based models for describing evolution of one-dimensional expansion with time[J]. Chinese Journal of Geotechnical Engineering, 2020, 42(4): 737-744. DOI: 10.11779/CJGE202004017

基于化学反应动力学方程的一维膨胀时程模型

Chemical reaction kinetics based models for describing evolution of one-dimensional expansion with time

  • 摘要: 基于膨胀土的微观膨胀机理,利用二级化学反应动力学方程推导出膨胀土的两种膨胀时程模型:双曲线模型和Logistic模型。前者为两参数模型,其参数物理意义明确;后者为三参数模型,尚有物理意义不明确的参数。通过室内一维膨胀率试验研究了初始含水率和干密度对膨胀时程曲线的影响规律,并对两个模型进行比较。结果表明:①双曲线模型与Logistic模型均能准确地描述膨胀时程曲线;②双曲线模型还可进一步用于预测不同初始含水率和干密度下的膨胀时程曲线;③预测曲线与试验数据具有较好的一致性,且参数的校正过程简单,便于工程应用。推导的膨胀时程模型对于描述膨胀土浸水饱和过程中的体变演化规律具有重要的理论意义。

     

    Abstract: Two models for describing the evolution of one-dimensional expansion of expansive soils with time are derived based on the second-order chemical reaction kinetic equation, namely, hyperbolic model and Logistic model. The former has two parameters which have clear physical meanings, while the latter has three parameters among which one has an unclear physical meaning. One-dimensional swelling tests on the specimens with different initial water contents and dry densities are conducted to obtain swelling strain-time curves, and the fitting effects using the two models are compared. The results show that both models can accurately describe the swelling strain-time curves. Moreover, the hyperbolic model can also be used to predict the expansion time-history curves of the specimens with different initial water contents and dry densities. The predicted curves have good consistency with the experimental data, and the parameter correction process is simple, which is convenient for engineering applications. The expansion time-history model deduced in this study has important theoretical significance for describing the evolution laws of volume change of expansive soils during the process of water immersion saturation.

     

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